Belladonna (Sorry, late post but this NM seems to be of high interest.)
General spawn time 1hr20min to 1hr30min. Have yet to see it spawn any earlier or any later. Spawns near the ledge at G-7 G-8, but has been reported to pop as far south as G-9 before the path cuts to the right.
I've only seen it pop @G-8 myself, near the scattered rocks. Very easy to kill THF75/NIN37, didn't even need to use eva build. DE pretty much takes a good chunk out of it. Seems to be a purely timed spawn. Sat there with two other campers and we didn't touch a thing. Just pops among the others. if you're really worried about missing the pop, you could try /RNG. Just bring an eva build I suppose.